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By far, the most common reasons for the condyle to be held in a partially translated location are a lateral pterygoid myospasm, TMJ in ammation, or a combination of these disorders.2 When the TMJ s retrodiscal tissue is in amed, it can physically push the condyle forward or the lateral pterygoid muscle can be in a state of protective splinting3 in which the patient subconsciously holds the condyle forward to avoid compressing the in amed retrodiscal tissue. When TMJ in ammation is the sole cause for the patient s inability to occlude in MI, the lateral pterygoid muscle is healthy and the patient would not have

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in which the CH2 SiCl2 n precursor is prepared by a Grignard reaction with Cl3 SiCH2 Cl, the hydride polymer prepared by LiAlH4 reduction has SiH3 CH2 , SiH2 CH2 , DSiHCH2 , and SiCH2 units in the approximate ratios of 2:8:20:11 This hyperbranched polymer with a carbosilane backbone is then crosslinked with either vinyl or allyl groups At the 25 10% levels, these crosslinks do not give any substantial excess carbon on pyrolysis at 1000 C with a 70 80% overall ceramic yield Because of the high yield, the stability in air, and its uidity, the product has found applications as a matrix source for silicon-carbide- ber-reinforced/SiC matrix composites as well as for joining silicon carbide ceramics The allyl crosslinked preceramic polymer is being manufactured by Star re Systems in Watervliet, NY.

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The pure version, synthesized by ring-opening polymerization of the dimeric Cl2 SiCH2 with a K2 PtCl6 catalyst followed by the same LiAlH4 reduction, is too expensive for commercialization, even with its higher ceramic yield The other 1:1 possibility, polymethylsilane SiCH3 H n , can provide 70 75% ceramic yields of fairly pure SiC at 900 C, although it contains some of the C5 H5 2 Ti CH3 2 or analogous Zr catalyst used in the polymer synthesis A slight variation using a [ CH3 SiH 08 CH3 Si 02 ]n crosslinked copolymer and 06% C5 H5 2 ZrH2 catalyst in hexane under re ux for 2 h caused even more crosslinking (the fraction of CH3 SiH units decreased from 08 to about 06).

Patients with this disorder present with some similarities to patients with a lateral pterygoid myospasm; i.e., both patients have limited opening, and their contralateral and protrusive movements are generally restricted. Fortunately there are many differences that enable practitioners to separate these diagnoses clinically; e.g., a patient with an acute TMJ disc displacement without reduction generally can close his or her teeth into maximum intercuspation without pain.

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The old versions (prior to V9) of Crystal Reports have the limitation for the string... upgrade your Crystal Reports to version 9 in order to add powerful QRCode  ...

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Crystal Reports QR Codes
Joined: 19 Mar 2008. Location: United States Online Status: Offline Posts: 36, Quote snufse Reply bullet Topic: QR Codes Posted: 02 May 2012 ...

Pyrolysis under argon (1500 C, 5 h) of the orange solid residue after solvent removal produced a black ceramic in 72% ceramic yield with 98% SiC, 16% ZrC, and 04% Si with good properties Other examples of SiC precursors can be given, such as the use of the thermolysis of [Si(i -butyl)2 CH2 ]n to approximate the SiH2 CH2 n composition About 75% of the i -butyl groups are eliminated as i -butene, producing a copolymer of about half SiH2 CH2 and about half [Si(i -butyl)HCH2 ] units at 420 C, and further heating eliminates the remaining i -butyl groups and hydrogen to yield a nearly stoichiometric silicon carbide at about 900 C Other modi cations include the deliberate addition of another tetravalent metal, titanium, to disrupt crystallization for uses requiring amorphous ceramic type material.

9.25 4.85 6.50 2.50 0.30 2.03 6.70 3.26 1.82

Note that simple linear polymers generally fail to provide a substantial ceramic yield unless a precuring crosslinking step is involved..

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